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1013, 987 cm-1 , 1H-NMR (300 MHz, CDC13): δ = 1.55, 1.62, 1.82, 1.85, 2.07, (5s, 15H, 1-AdmH), 1.85 (s, 3H, NCOCH3), 2.33 (s, 3H, OCOCH3), 5.50-5.56 (m, 2H, H-3, H-6), 5.63 (d, J = 11.4 Hz, 1H, OH), 6.28 [...] supplied. 1-Adamantanethiol (1-AdmSH) was prepared by the literature method (Khullar and Bauer, 1971).
Figure 1: Chemical structures of 1,2,3,4- and 1,2,3,6-tetrahydropyridines
Synthesis of N-acetyl-2-(1-adamantyl- [...] J = 2.1 Hz, 1H, H-2), 6.35 (d, J = 3.0 Hz, 1H, H-5), 7.25 (s, 5H, PhH). 13C-NMR (75 MHz, CDC13) : δ = 20.8 (NCOCH3), 21.7 (OCOCH3), 29.3 (3 × CH-1-Adm), 35.0, 36.0 (6 × CH2-1-Adm), 57.8 (Cqua-1- Adm), …